11.8 Polymers

2026 Syllabus Objectives

  1. Core: Define polymers as large molecules built up from many smaller molecules called monomers
  2. Core: Describe the formation of poly(ethene) as an example of addition polymerisation using ethene monomers
  3. Core: State that plastics are made from polymers
  4. Core: Describe how the properties of plastics have implications for their disposal
  5. Core: Describe the environmental challenges caused by plastics, limited to: (a) disposal in landfill sites (b) accumulation in oceans (c) formation of toxic gases from burning
  6. Supplement: Identify the repeat units and/or linkages in addition polymers and in condensation polymers
  7. Supplement: Deduce the structure or repeat unit of an addition polymer from a given alkene and vice versa
  8. Supplement: Deduce the structure or repeat unit of a condensation polymer from given monomers and vice versa, limited to: (a) polyamides from a dicarboxylic acid and a diamine (b) polyesters from a dicarboxylic acid and a diol
  9. Supplement: Describe the differences between addition and condensation polymerisation
  10. Supplement: Describe and draw the structure of: (a) nylon, a polyamide (b) PET, a polyester. The full name for PET, polyethylene terephthalate, is not required
  11. Supplement: State that PET can be converted back into monomers and re-polymerised
  12. Supplement: Describe proteins as natural polyamides and that they are formed from amino acid monomers with the general structure where R represents different types of side-chain
  13. Supplement: Describe and draw the structure of proteins

What Are Polymers? 🔬

Polymers are large organic molecules made up of many small repeating units called monomers joined together through a process called polymerisation.

🔑 Key Definition: A polymer is a substance consisting of very large molecules made by polymerising a large number of repeating units, or monomers.

🔑 Key Definition: A monomer is a small molecule, such as ethene, which can be polymerised to make a polymer.

Natural and Synthetic Polymers

Polymers are found both in nature and are manufactured synthetically:

Natural polymers include:

  • Proteins
  • Carbohydrates
  • Wood
  • Natural rubber

Synthetic polymers, often called plastics, are found everywhere in modern technological societies, ranging from car and aircraft components to packaging and clothing.

Types of Polymers

Homopolymers contain just one type of monomer:

  • Poly(ethene)
  • Poly(propene)
  • Poly(chloroethene)

Copolymers are made of two or more different types of monomer:

  • Nylon (made from two monomers)
  • Biological proteins (made from 20 different amino acid monomers)

The repeating units in polymers can be repeated anywhere from about a hundred to more than a million times.

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