8.2 Group I Properties

2026 Syllabus Objectives

  1. Core: Describe the Group I alkali metals, lithium, sodium and potassium, as relatively soft metals with general trends down the group, limited to:

    • (a) decreasing melting point
    • (b) increasing density
    • (c) increasing reactivity
  2. Core: Predict the properties of other elements in Group I, given information about the elements


🔬 Introduction to Group I – The Alkali Metals

Group I metals are commonly known as the alkali metals. These metals exhibit unique physical and chemical properties that distinguish them from other elements in the periodic table.

General Characteristics

The alkali metals share several common features:

  • They are relatively soft solids that can be cut with a knife
  • They have low melting points compared to other metals
  • They have low densities (some can even float on water)
  • They are highly reactive metals
  • They are stored in oil to prevent reactions with oxygen and water vapour in the air

Important: When freshly cut with a knife, all alkali metals display a light-grey, silvery surface which quickly tarnishes and becomes dull due to rapid oxidation in air.


📊 Physical Properties and Trends

The physical properties of Group I metals change in a predictable pattern as we move down the group.

Key Physical Properties Table

MetalElectronic ConfigurationDensity / g/cm3\text{g/cm}^3Melting Point / °C°\text{C}Boiling Point / °C°\text{C}Hardness
Lithium2,10.531811342fairly soft
Sodium2,8,10.9798883soft
Potassium2,8,8,10.86*63760very soft

*Note: The density value for sodium is higher than would be expected from the general trend.

📉 Trend 1: Decreasing Melting Points

As we move down Group I, the melting points decrease:

  • Lithium: 181°C181\,°\text{C}
  • Sodium: 98°C98\,°\text{C}
  • Potassium: 63°C63\,°\text{C}

The pattern shows that each successive element has a lower melting point than the one above it. Similarly, boiling points also decrease down the group.

📈 Trend 2: Increasing Density

As we move down Group I, the density generally increases:

  • Lithium: 0.53g/cm30.53\,\text{g/cm}^3
  • Sodium: 0.97g/cm30.97\,\text{g/cm}^3
  • Potassium: 0.86g/cm30.86\,\text{g/cm}^3

Although the general trend is increasing density, this pattern is slightly obscured because sodium's density is higher than would be expected from a smooth progression.

🔪 Trend 3: Increasing Softness

The metals become progressively softer as we descend the group:

  • Lithium is fairly soft
  • Sodium is soft
  • Potassium is very soft

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